Technical Data Sheet for Geopolymeric cement type (Potassium, Calcium) – Poly(sialate-siloxo) / (K,Ca) – (Si-O-Al-O-Si-O-), Si:Al=2:1
Further details in Davidovits’ book, GEOPOLYMER Chemistry & Applications, Part III, Properties, Chapters 15 to 18, GEOCISTEM , GLOBAL WARMING, and also previous papers in the Geopolymer Library.
Tested on standard sand mortar prisms:
- setting: 10 hours at -20°C to 7-60 minutes at +20°C.
- shrinkage during setting: <0,05%, not measurable.
- compressive strength (uniaxial): > 90 MPa at 28 days (for high early strength formulation, 20 MPa after 4 hours).
- flexural strength: 10-15 MPa at 28 days (for high early strength 10 MPa after 24 hours).
- Young Modulus: > 2 GPa.
- freeze-thaw: mass loss < 0,1% (ASTM 4842), strength loss < 5% after 180 cycles.
- wet-dry: mass loss < 0,1% (ASTM 4843).
- pH: crushed and powdered, 11-11,5 after 5 minutes in deionized water (compared to Portland cement: 12 to 12,5, and granite: 11).
- leaching in water, after 180 days: K2O < 0,015%.
- water absorption: < 3%, not related to permeability.
- hydraulic permeability: 10-10 m/s.
- Sulfuric acid, 10%: mass loss 0,1% per day.
- chlorhydric acid 5%: mass loss 1% per day.
- KOH 50%: mass loss 0,02% per day.
- ammoniac solution: no mass loss.
- sulfate solution: shrinkage 0,02% at 28 days.
- alkali-aggregate reaction: no expansion after 250 days, -0,01% (compared to Portland Cement with 1% Na2O, +1,5%).
- linear expansion: < 5.10-6/K.
- heat conductivity: 0,2 to 0,4 W/Km.
- specific heat: 0,7 to 1,0 kJ/kg.
- electrical conductivity: strongly dependent on humidity.
- thermal stability:
- mass loss < 5% up to 1000°C.
- strength loss < 20% at 600°C, < 60% at 1000°C
Other values:
- D.T.A.: endothermic at 250°C (zeolitic water).
- MAS-NMR spectroscopy:
- 29Si: SiQ4, major resonance at -94,5 ± 3ppm.
- 27Al: AlQ(4Si), major narrow resonance at 55 ± 3ppm.
- Energy consumption: SEC for cement 1230-1310 MJ/tonne (compared to Portland clinker 3500 MJ/tonne).
- CO2 emission during manufacture: 0,180 t/tonne of cement (compared to Portland clinker 1,0 t/tonne).